a mushroom, Psilocybe mexicana, of Mexico and the southwestern U.S., containing the hallucinogen psilocybin.
(informal) any of various types of fungi that contain a hallucinogenic substance, esp Psilocybe mexicana, which contains psilocybin

any toadstool with hallucinogenic properties from psilocybin, e.g. the liberty cap or fly agaric

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